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Synthesis of 10-Hydroxy- and 9-Oxo-2e-Decenoic Acids from Oleic Acid
Authors:R. Ya. Kharisov  O. V. Botsman  L. P. Botsman  N. M. Ishmuratova  G. Yu. Ishmuratov  G. A. Tolstikov
Affiliation:(1) Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, 450054 Ufa, pr. Oktyabrya, 71
Abstract:A practical synthesis of biologically active 10-hydroxy- and 9-oxo-2E-decenoic acids, components of mandibular gland secretion of honeybee (Apis mellifera L.), is developed using ozonolysis-reduction of oleic acid and 1,9-diacetoxynon-1-ene in the key steps.
Keywords:8-acetoxyoctanal  10-hydroxy-2E-decenoic acid  1,9-diacetoxynon-1-ene  ozonolysis  9-oxo-2E-decenoic acid  oleic acid  honeybee  Doebner reaction  mandibular gland secretion  synthesis
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