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Ternary complexes of palladium(II) and selected amines
Authors:Mohamed M Shoukry  Ibrahim M Kenawy  Ibrahim H El-Haj
Institution:(1) Department of Chemistry, Faculty of Science, University of United Arab Emirate, P. O. Box 17551, Al-Ain, United Arab Emirate;(2) Department of Chemistry, Faculty of Science, Cairo University, Giza, Egypt;(3) Present address: Department of Chemistry, Faculty of Science, Mansoura University, Egypt
Abstract:Summary The formation and equilibria of the binary and ternary palladium(II) complexes of diethylenetriamine (dien) with other selected amines have been investigated. The results of pH titration measurements allowed the calculation of equilibrium constants, characteristic for the binary and ternary complexes formed. The concentration distribution of various complex species was evaluated and the chelation mode ascertained by conductivity measurements.
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