| 新型杯[4]芳烃衍生物的合成及其氨基酸萃取性能 |
| |
| 引用本文： | 杨发福,蔡秀琴,郭红玉,陈希磊.新型杯[4]芳烃衍生物的合成及其氨基酸萃取性能[J].分子科学学报,2006,22(2):96-99. |
| |
| 作者姓名： | 杨发福 蔡秀琴 郭红玉 陈希磊 |
| |
| 作者单位： | 福建师范大学化学与材料学院,福建,福州,350007 |
| |
| 基金项目： | 中国科学院资助项目;福建省自然科学基金 |
| |
| 摘 要： | 杯4]-1,3-二乙酸乙酯衍生物(1)与水合肼反应生成杯4]芳烃酰肼衍生物(2),化合物(2)与异硫氰酸苯酯反应得到含酰胺和硫脲单元的新型杯4]芳烃衍生物(3).总产率达70%.系列氨基酸萃取实验表明化合物(3)对异亮氨酸有较好的选择性萃取能力.
|
| 关 键 词： | 杯[4]芳烃衍生物 合成 氨基酸 萃取 |
| 文章编号： | 1000-9035(2006)02-0096-04 |
| 收稿时间： | 04 22 2005 12:00AM |
| 修稿时间： | 2005年4月22日 |
Synthesis and amino acids extracting properties of novel calix[4]arene derivatives |
| |
| YANG Fa-fu,CAI Xiu-qin,GUO Hong-yu,CHEN Xi-lei.Synthesis and amino acids extracting properties of novel calix[4]arene derivatives[J].Journal of Molecular Science,2006,22(2):96-99. |
| |
| Authors: | YANG Fa-fu CAI Xiu-qin GUO Hong-yu CHEN Xi-lei |
| |
| Institution: | College of Chemistry and Materials Science, Fujian Normal University,Fuzhou 350007,China |
| |
| Abstract: | Calix4]arene hydrazide derivative,(2) was obtained by the reaction of calix4]-1,3-bis-ethylacetate (1) with hydrazine hydrate. Treatment of compound (2) with phenyl isothiocyanate, a new calix4]arene derivative (3) containing amides and thiourea units was synthesized. The total yield was as high as 85%. The extraction experiments for amino acids showed that compound (3) exhibited good selective extraction ability for isoleucine. |
| |
| Keywords: | calix[4]arene derivative synthesis amino acid extraction |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
