Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion |
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| Authors: | Li Xiaofei Ni Chengbao Song Haibing Cui Chunming |
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| Affiliation: | State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China. |
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| Abstract: | Reaction of LAl[eta2-(CSiMe3)2] (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with carbon monoxide and tert-butyl isocyanide afforded unique AlC3 aluminacyclobutenes via insertion into one of the aluminium-carbon bonds. |
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