Thermal studies on palladium alkyl xanthates |
| |
| Authors: | C.G. Sceney J.O. Hill R.J. Magee |
| |
| Affiliation: | Department of Inorganic and Analytical Chemistry, La Trobe University, Bundoora, Melbourne, Vict. 3083 Australia |
| |
| Abstract: | Eleven palladium(II) alkylxanthates: Pd(ROCSS)2 [RMe, Et, nPr, iPr, nBu, iBu, tBu, nAm, iAm, nHex and cyclohex], have been prepared and their thermal properties investigated by thermogravimetric analysis. The complexes, although volatile under vacuum (10?2 mm Hg), decompose without volatilization at normal atmospheric pressure leaving a residue of palladium metal at 950°C. The intermediate decomposition products were identified mass spectrometrically and a thermal decomposition mechanism is proposed. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
