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Construction of Heterojunction Nanowires from Polythiophene/Polypyrrole for Applications as Efficient Switches
Authors:Yanbing Guo  Prof Yuliang Li  Dr Yongjun Li  Dr Huibiao Liu  Guoxing Li  Yingjie Zhao  Haowei Lin
Institution:1. CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, (P.R. China), Fax: (+86)?10‐82616576;2. Graduate School, Chinese Academy of Sciences, Beijing 100190 (P.R. China)
Abstract:The design and fabrication of PTh–PPY heterojunction nanowires that exhibits smart responses to electrochemical redox potentials is described. In their oxidized state, PTh–PPY nanowires act as resistors, whilst in their reduced state, they acts as diodes. Furthermore, the electrical transport mode can be reversibly changed by alternately exposing the nanowires to negative and positive potentials. Constructing full‐organic heterojunction nanowires with smart, controllable properties will contribute to the development of intelligent organic devices and organic–electronic circuits on the nanoscale.
Keywords:conducting materials  electrochemistry  nanostructures  redox chemistry  template synthesis
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