Reaction of coordinated phosphines—II: Arylation of substituted olefins by palladium(II) acetate and triarylphosphine |
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| Authors: | T Yamane K Kikukawa M Takagi T Matsuda |
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| Institution: | Department of Organic Synthesis, Faculty of Engineering, Kyushu University, Hakozaki, Higashiku, Fukuoka, 812, Japan |
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| Abstract: | Phenylation of 1-octene, cyclohexene, styrene, acrylonitrile, vinyl acetate, ethyl acrylate, and ethyl but-3-enoate with Pd(PAr3)2(OAc)2 was carried out in acetic acid at 50°. para-Substituted triphenylphosphine palladium acetate complex produced corresponding para substituted phenyl derivatives. |
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