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Efficient synthesis of 4‐heteroaryl‐substituted triphenylamine derivatives via a ligand‐free Suzuki reaction
Authors:Chun Liu  Yonghua Wu  Na Han  Jieshan Qiu
Affiliation:State Key Laboratory of Fine Chemicals, Dalian University of Technology, , Dalian, 116024 People's Republic of China
Abstract:This paper reports an efficient synthesis of 4‐heteroaryl‐substituted triphenylamine derivatives via the palladium‐catalyzed Suzuki reaction of heteroaryl halides with 4‐(diphenylamino)phenylboronic acid in ethylene glycol under ligand‐free and aerobic conditions. These derivatives are important structural motifs for use in dye‐sensitized solar cells and organic electroluminescence materials. Copyright © 2011 John Wiley & Sons, Ltd.
Keywords:palladium  ligand‐free  heteroaryl compound  Suzuki reaction  triphenylamine derivatives
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