Electronic structure of the metallic tungsten bronces Lax−yGdyWO3 (ESR measurements) |
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| Authors: | G Sperlich K Jansen G Bang |
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| Institution: | 1. II. Physikalisches Institut, Technische Hochschule Darmstadt, D-61 Darmstadt, Germany |
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| Abstract: | ESR- and magnetic susceptibility measurements on the metallic bronce Lax?yGdyWO3 (x = 0.10, 0.15; y ? x) prove that the 6s25d1 orbitals of the rare earth (RE) ions do not contribute to the conduction band of the WO3 complex. The RE ions are completely decoupled from it; crystal field effects, therefore, are observable. |
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