The Hg2 (A3Ou− → X1Σg+) and (A31u → X1Σg+) fluorescence |
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| Authors: | AC Vikis DJ Le Roy |
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| Institution: | Department of Chemistry, Lash Miller Chemical Laboratories, University of Toronto, Toronto, Ontario, Canada. M5S 1A1 |
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| Abstract: | The fine structure emission sepctrum near 5500 Å attributed to the Hg2 (A3Ou? → X1Σg+) transition is shown to be strikingly similar to the HgCl (B2Σ+ → X2Σ+) emission spectrum sensitized by Hg(63Po) metastables. The correct Hg2 (A3Ou? → X1Σg+) emission spectrum at 4850 Å was re-examined and confirmed to be a continuous one. It is suggested that the fine structure arose from the sensitization of a chlorine containing impurity. |
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