Resonance paramagnetique electronique du manganese divalent dans ZnAl2O4 |
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Authors: | Edgar Soulié Maurice Drifford Paul Rigny |
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Institution: | Division de Chimie-C.E.N. Saclay, B.P. No.2, 91190-Gif-sur-Yvette, France |
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Abstract: | The electron paramagnetic resonance spectrum of a single crystal of ZnAl2O4 (spinel structure) doped with manganese displays a fine structure characteristic of a purely cubic crystal field. Contrary to MgAl2O4: Mn2+, where the degree of inversion is sizable, ZnAl2O4 therefore is a normal spinel. |
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