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太阳能高温电解水蒸气制氢系统热力学分析
引用本文:黄志刚,李增耀,陶文铨.太阳能高温电解水蒸气制氢系统热力学分析[J].工程热物理学报,2009,30(9).
作者姓名:黄志刚  李增耀  陶文铨
作者单位:1. 西安交通大学动力工程多相流国家重点实验室,陕西,西安,710049;第二炮兵工程学院,陕西,西安,710025
2. 西安交通大学动力工程多相流国家重点实验室,陕西,西安,710049
基金项目:国家自然科学基金重点项目 
摘    要:本文对太阳能高温电解水蒸气制氢系统进行了设计.该系统以太阳能为唯一的一次能源,采用太阳能分频技术,提供高温电解水蒸气制氢所需的电能和热能.此外,利用余热回收器回收电解产物的余热.热力学分析表明:(1)系统制氢效率可达34.8%;(2)太阳能聚光-分频热电联产装置是系统能量和(火用)损失最大的环节.提高电解温度和降低操作电压可减小电解环节的(火用)损失.

关 键 词:太阳能制氢  分频  高温电解  热力学分析

THERMODYNAMIC ANALYSIS OF SOLAR HYDROGEN PRODUCTION WITH HIGH TEMPERATURE STEAM ELECTROLYSIS
HUANG Zhi-Gang,LI Zeng-Yao,TAO Wen-Quan.THERMODYNAMIC ANALYSIS OF SOLAR HYDROGEN PRODUCTION WITH HIGH TEMPERATURE STEAM ELECTROLYSIS[J].Journal of Engineering Thermophysics,2009,30(9).
Authors:HUANG Zhi-Gang  LI Zeng-Yao  TAO Wen-Quan
Abstract:In this paper,a new solar hydrogen production system with high temperature steam electrolysis(HTSE)is designed.The system utilizes solar energy as the only prime energy source.Solar concentrating and spectral beam splitting technologies are employed to provide electricity and thermal energy for high temperature steam electrolysis.Additionally,the heat of electrolysis products is recuperated by heat exchanger.Thermodynamic analysis results show that (1) the system hydrogen production efficiency can reach 34.8%,and (2) the solar concentrating and spectral beam splitting device is the principal thermodynamics loss source.It is found that an increase in temperature and decrease in operating voltage can reduce the exergy destruction in the electrolysis cell.
Keywords:solar hydrogen production  beam splitting  high temperature electrolysis  thermodynamic analysis
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