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Reaction of secondary amines with acetylenic γ-hydroxyaldehydes and γ-ketoacetals
Authors:Medvedeva  A. S.  Safronova  L. P.  Kalikhman  I. D.  Voronkov  M. G.
Affiliation:1.Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR
;
Abstract:
1. The reaction of acetylenic gamma-hydroxyaldehydes with secondary amines in a methanolic medium leads to the formation of 2-methoxy-4-dialkylamino-5,5-dialkyldihydrofurans.
2. Protection of the hydroxyl group in the acetylenic gamma-hydroxyketones allows one to add diethylamine and obtain previously unknown enamines.
Keywords:
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