| One-Pot Hydrothermal Synthesis of Two New Copper（Ⅱ） Complexes with 4-Carboxyphenoxy Acetic Acid |
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| 引用本文： | 庄文娟 孙长艳 金林培. One-Pot Hydrothermal Synthesis of Two New Copper（Ⅱ） Complexes with 4-Carboxyphenoxy Acetic Acid[J]. 中国化学, 2006, 24(11): 1554-1558. DOI: 10.1002/cjoc.200690291 |
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| 作者姓名： | 庄文娟 孙长艳 金林培 |
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| 作者单位： | School of Chemistry, Beijing Normal University, Beijing 100875, China |
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| 基金项目： | Project supported by National Natural Science Foundation of China （Nos. 20331010, 20501003）. |
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| 摘 要： | The one-pot hydrothermal reaction of CuCl2 with H2CPOA and 4,4＇-bpy results in two new coordination polymers, [Cu（CPOA）（4,4＇-bpy）（H2O）2]·1.5H2O （1） and [Cu2（HCPOA）4（4,4＇-bpy）4] （2） （H2CPOA=4-carboxyphenoxy acetic acid, 4,4＇-bpy=4,4＇-bipyridine） since CPOA^2- anions reach equilibrium with HCPOA^- anions in the reaction system. The crystal structure of 1 shows a triple interpenetration CdSO4-like net with 1D channel, in which lattice water molecules are located. Complex 2 is a ladder-like 1D double chain structure assembled through coordination bonds and O—H…N hydrogen bonds.
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| 关 键 词： | 4-羧基苯氧基醋酸 4 4＇-二嘧啶 铜（Ⅱ）配位化合物 一壶水热合成 |
| 收稿时间： | 2006-03-21 |
| 修稿时间： | 2006-03-212006-07-05 |
One‐Pot Hydrothermal Synthesis of Two New Copper(II) Complexes with 4‐Carboxyphenoxy Acetic Acid |
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| ZHUANG, Wen-Juan, SUN, Chang-Yan, JIN, Lin-Pei. One‐Pot Hydrothermal Synthesis of Two New Copper(II) Complexes with 4‐Carboxyphenoxy Acetic Acid[J]. Chinese Journal of Chemistry, 2006, 24(11): 1554-1558. DOI: 10.1002/cjoc.200690291 |
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| Authors: | ZHUANG Wen-Juan SUN Chang-Yan JIN Lin-Pei |
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| Abstract: | The one‐pot hydrothermal reaction of CuCl2 with H2CPOA and 4,4′‐bpy results in two new coordination polymers, [Cu(CPOA)(4,4′‐bpy)(H2O)2]·1.5H2O ( 1 ) and [Cu2(HCPOA)4(4,4′‐bpy)4] ( 2 ) (H2CPOA?4‐carboxyphenoxy acetic acid, 4,4′‐bpy?4,4′‐bipyridine) since CPOA2? anions reach equilibrium with HCPOA? anions in the reaction system. The crystal structure of 1 shows a triple interpenetration CdSO4‐like net with 1D channel, in which lattice water molecules are located. Complex 2 is a ladder‐like 1D double chain structure assembled through coordination bonds and O–H···N hydrogen bonds. |
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| Keywords: | 4‐carboxyphenoxy acetic acid 4,4′‐bipyridine one‐pot reaction copper(II) coordination polymer |
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