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Cross-recyclization of 4-aryl-2,6-diamino-4<Emphasis Type="Italic">H</Emphasis>-thiopyran-3,5-dicarbonitriles with 1-morpholino-1-cyclopentene: New route to 4-aryl-2-thioxo-2,5,6,7-tetrahydro-1<Emphasis Type="Italic">H</Emphasis>-[1]pyrindine-3-carbonitriles and their derivatives
Authors:V D Dyachenko  A D Dyachenko
Institution:(1) Taras Shevchenko National Pedagogical University, Lugansk, 91011, Ukraine
Abstract:Reaction of 4-aryl-2,6-diamino-4H-thiopyran-3,5-dicarbonitriles with 1-morpholino-1-cyclopentene led to the formation of 4-aryl-2-thioxo-2,5,6,7-tetrahydro-1H-1]pyrindine-3-carbonitriles used in the synthesis of substituted 2-alkylsulfanyl-4-aryl-6,7-dihydro-5H-1]pyrindine-3-carbonitriles and 3-amino-4-aryl-6,7-dihydro-5H-cyclopentabthieno3,2-e]pyridines.
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