2,6-萘二甲酸构筑配合物的研究进展

2,6-萘二甲酸是一个具有多个配位原子的线性刚性配体,迄今,已报道的2,6-萘二甲酸构筑的配合物有100多个,它们展现了丰富的拓扑结构和潜在的应用价值。本文总结了2,6-萘二甲酸配体的结构特点以及配位模式,并按照金属离子的种类对2,6-萘二甲酸配合物进行分类归纳总结。着重介绍了2,6-萘二甲酸配合物在气体吸附分离、光致发光、磁性及多相催化方面的应用性质,对该类配合物的发展前景进行了展望。

The Advance of 2,6-naphthalenedicarboxylic acid-Based Coordination Polymers

2,6-naphthalenedicarboxylic acid is an linear and rigid ligand with multiple coordinating atoms. up to now, more than 100 2,6-naphthalenedicarboxylic acid-based coordination polymers have been reported. These coordination polymers show the abundant topological structures and potential application values, however, the relative review based on 2,6-naphthalenedicarboxylic acid-based coordination polymers were not reported. This paper mainly summarizes the structural characteristics and coordination modes of 2,6-naphthalenedicarboxylic acid ligand, and systematic reviews the research advance of 2,6-naphthalenedicarboxylic acid-based coordination complexes according to various species of metal ions in recent years. We focuses on the application properties of 2,6-naphthalenedicarboxylic acid-based coordination polymers in the gas adsorption and separation, photoluminescence, magnetism and heterogeneous catalysis aspects, Finally, the research prospects of these coordination polymers are prospected. The synthesis, properties and development status of the 2,6-naphthalenedicarboxylic acid-based coordination polymers can be well known through this review, and it is of great significance for the study of this type of ligands.