| 乙酰丙酮-5,10,15,20-四-(对氯苯基)卟啉稀土配合物的制备和性质 |
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| 引用本文： | 刘国发.乙酰丙酮-5,10,15,20-四-(对氯苯基)卟啉稀土配合物的制备和性质[J].高等学校化学学报,1985,6(7):569. |
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| 作者姓名： | 刘国发 |
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| 作者单位： | 吉林大学理论化学研究所 |
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| 摘 要： | 用丙酸做溶剂,吡咯与对氯笨甲醛反应制备5,10,15,20-四-(对氯苯基)卟啉(p-Cl)Tpp;后者与稀土乙酰丙酮配合物Ln(acac)3·3H2O在1,2,4-三氯苯中反应制得乙酰丙酮-5,10,15,20-四-(对氯苯基)卟啉稀土配合物Ln(p-Cl)Tppacac;并做了元素分析、UV、IR和PMR等性质的研究。
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| 收稿时间： | 1984-01-26 |
Preparation and Properties of Acetylacetonate 5,10,15, 20-Tetra-(p-Chlorophenyl) Porphyrin Rare Earth Complexes |
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| Liu Guofa.Preparation and Properties of Acetylacetonate 5,10,15, 20-Tetra-(p-Chlorophenyl) Porphyrin Rare Earth Complexes[J].Chemical Research In Chinese Universities,1985,6(7):569. |
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| Authors: | Liu Guofa |
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| Institution: | Institute of Theoretical Chemistry, Jilin University, Changchun |
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| Abstract: | Acetylacetonate-5,10,15,20-tetra-(p-chlorophenyl) porphyrin rare earth complexes Ln (p-Cl) Tppacac (Ln:Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb and Lu) have been synthesized by the direct reaction of (p-Cl) Tpp with Ln(acac)3·3H2Oin1,2,4-trichlorobenzene.Their properties were discussed simply. |
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