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Facile and effective approach for oxidation of boronic acids
Authors:Ravindra B Wagh  Jayashree M Nagarkar
Institution:Department of Chemistry, Institute of Chemical Technology, Matunga, Mumbai 400019, India
Abstract:This present work illustrates facile and effective approach for oxidation of boronic acids using environmentally benign dimethyl carbonate (DMC) as a solvent with H2O2 as an oxidant at room temperature. In contrast to previous reaction reports, which make use of metal catalyst, hazardous reagent and oxidants that creates environmental concern. This method provides good to excellent yield of products and showed better tolerance towards various functional groups present on boronic acids. Moreover, this developed process is an alternative in terms of inexpensive, non toxic and easy reaction conditions.
Keywords:Oxidation  Synthetic organic  Boronic acid  Dimethyl carbonate  Peroxides
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