Immobilization of palladium nanoparticles on ionic liquid-triethylammonium chloride functionalized magnetic nanoparticles: As a magnetically separable,stable and recyclable catalyst for Suzuki-Miyaura cross-coupling reactions |
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Authors: | Hojat Veisi Mozhgan Pirhayati Ali Kakanejadifard |
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Institution: | 1. Department of Chemistry, Payame Noor University (PNU), Tehran, Iran;2. Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, Iran |
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Abstract: | A facile procedure was applied to successfully synthesize novel Pd nanoparticles immobilized on triethanolamine-functionalized magnetic nanoparticles Fe3O4/IL/Pd]. Diverse characterizations (HR-TEM, XRD, FT-IR, TGA, EDX, FE-SEM, ICP, XPS and VSM) were carried out to identify intrinsic traits of the nanoparticles. At room temperature, Fe3O4/IL/Pd demonstrated high catalytic activity toward Suzuki-Miyaura cross-coupling reactions in aqueous solution. Based on the results, Fe3O4/IL/Pd acted as zwitterionic IL-type heterogeneous catalyst, which could be separated from the reaction mixture, conveniently. Moreover, it exhibited excellent recyclability for at least eight cycles without considerable loss of its activity. |
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Keywords: | Magnetic Nanoparticles Palladium Heterogeneous nanocatalyst Suzuki |
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