Convenient preparation of dichloromethyl alkyl ethers |
| |
| Authors: | Yoshikazu Kimura Takuya Warashina |
| |
| Institution: | Research and Development Department, Iharanikkei Chemical Industry Co. Ltd., Kambara, Shimizu-ku, Shizuoka 421-3203, Japan |
| |
| Abstract: | Dichloromethyl alkyl ethers have been synthesized from alkyl formates (C1–C4) and oxalyl chloride in the presence of catalytic amount of N-methylformanilide. N,N-Dimethylformamide is not suitable for the reaction. The method has the advantages of simple experimental procedure, which is applicable to large scale synthesis, without use of harmful reagents. |
| |
| Keywords: | Alkyl formate Oxalyl chloride Formylation Vilsmeier reagent |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
