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Extraction-spectrophotometric and radiometric investigation of the ternary ion-association complex of niobium(V) with pyrocatechol and triphenyl-tetrazolium chloride
Authors:A. Alexandrov  S. Kostova
Affiliation:(1) Department of Genral and Inorganic Chemistry, University of Plovdiv, Plovdiv, (Bulgaria)
Abstract:The optimum conditions for extraction of niobium(V) as a ternary ion-association complex with pyrocatechol and triphenyltetrazolium chloride(TTC) have been determined. The investigation of the composition has shown that the ratio Nb:proocatechol:TTC is 1:2:1 Kex, KD and beta have been determined radiometrically, using the chemical model. The influence of foreign ions on the extraction of the ion-association complex has been studied. A method for artifical mixture and steel containing niobium has been used.
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