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Multifunctional Redox Polymers: Electrochrome,Polyelectrolyte, Sensor,Electrode Modifier,Nanoparticle Stabilizer,and Catalyst Template
Authors:Christophe Deraedt  Amalia Rapakousiou  Yanlan Wang  Dr. Lionel Salmon  Melanie Bousquet  Prof. Didier Astruc
Affiliation:1. ISM, UMR CNRS N°5255, Univ. Bordeaux, 33405 Talence, cedex (France) http://astruc.didier.free.fr;2. Laboratoire de Chimie de Coordination UPR CNRS N°8241, 31077 Toulouse cedex (France);3. Laboratoire de Chimie des Polymères Organiques, UMR CNRS N° 5629, Univ. Bordeaux, 33607 Pessac, cedex (France)
Abstract:Simple “click” polycondensation metallopolymers of redox‐robust bis(ethynyl)biferrocene (biFc) and di(azido) poly(ethylene glycol) (PEG400 and PEG1000) were designed for multiple functions including improvement of water solubility and biocompatibility, the introduction of mixed valency and sensing capabilities, and as nanoparticle stabilizers for catalysis.
Keywords:biferrocenes  click chemistry  heterogeneous catalysis  nanoparticles  polymers
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