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Post‐Metallocenes in the Industrial Production of Polyolefins
Authors:M. Sc. Moritz C. Baier  Dr. Martin A. Zuideveld  Prof. Dr. Stefan Mecking
Affiliation:1. Department of Chemistry, Chair of Chemical Materials Science, University of Konstanz, Universit?tsstrasse 10, 78457 Konstanz (Germany) http://www.chemie.uni‐konstanz.de/agmeck/;2. Medium and High Throughput Polyolefin Research, SABIC, Science and Technology Center, Geleen, Urmonderbaan 22, P.O. 18, 6160 MD Geleen (Netherlands)
Abstract:Research on “post‐metallocene” polymerization catalysis ranges methodologically from fundamental mechanistic studies of polymerization reactions over catalyst design to material properties of the polyolefins prepared. A common goal of these studies is the creation of practically useful new polyolefin materials or polymerization processes. This Review gives a comprehensive overview of post‐metallocene polymerization catalysts that have been put into practice. The decisive properties for this success of a given catalyst structure are delineated.
Keywords:catalysis  industrial chemistry  polyolefins  post‐metallocenes
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