Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal–Organic Framework Thin Film |
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| Authors: | Chunjing Lu Prof Dr Teng Ben Shixian Xu Prof Dr Shilun Qiu |
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| Institution: | 1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China);2. Department of Chemistry, Jilin University, Changchun, 130012 (China) |
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| Abstract: | A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well‐defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g?1 and a high electric conductivity of 0.125 S cm?1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs. |
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| Keywords: | adsorption conducting polymers electrochemical synthesis metal– organic frameworks polyaniline |
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