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Metal‐Free Triplet Phosphors with High Emission Efficiency and High Tunability
Authors:Michael Koch  Karthikeyan Perumal  Dr Olivier Blacque  Dr Jai Anand Garg  Dr Ramanathan Saiganesh  Dr Senthamaraikannan Kabilan  Prof?Dr Kallupattu Kuppusamy Balasubramanian  Dr Koushik Venkatesan
Institution:1. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH‐8057 Zurich (Switzerland);2. Shasun Research Centre, 27 Vandaloor‐Kelambakkam Road, Keelakottaiyur, Chennai‐600048 (India);3. Department of Chemistry, Annamalai University, Annamalai Nagar, Chidambaram‐600002 (India)
Abstract:Design of highly efficient phosphorescent emitters based on metal‐ and heavy atom‐free boron compounds has been demonstrated by taking advantage of the singlet fission process. The combination of a suitable molecular scaffold and appropriate electronic nature of the substituents has been utilized to tailor the phosphorescence emission properties in solution, neat solid, and in doped PMMA thin films.
Keywords:dual emission  excimer  organic emitter  phosphorescence
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