A 2,6‐Bis(phenylamino)pyridinato Titanium Catalyst for the Highly Regioselective Hydroaminoalkylation of Styrenes and 1,3‐Butadienes |
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Authors: | Jaika Dörfler Till Preuß Alexandra Schischko Dr. Marc Schmidtmann Prof. Dr. Sven Doye |
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Affiliation: | Institut für Chemie, Universit?t Oldenburg, Carl‐von‐Ossietzky‐Strasse 9–11, 26111 Oldenburg (Germany) |
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Abstract: | The C? C bond forming catalytic hydroaminoalkylation of terminal alkenes, 1,3‐dienes, or styrenes allows a direct and highly atom efficient (100 %) synthesis of amines which can result in the formation of two regioisomers, the linear and the branched product. We present a new titanium catalyst with 2,6‐bis(phenylamino)pyridinato ligands for intermolecular hydroaminoalkylation reactions of styrenes and 1‐phenyl‐1,3‐butadienes that delivers the corresponding linear hydroaminoalkylation products with excellent regioselectivities. |
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Keywords: | 1,3‐dienes amines C H activation styrenes titanium |
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