Continuity of the temperature and derivation of the Gibbs canonical distribution in classical statistical mechanics |
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Authors: | R Rechtman O Penrose |
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Institution: | (1) Facultad de Ciencias, Universidad Nacional Autonoma de México, Ciudad Universitaria, Mexico City, Mexico;(2) Faculty of Mathematics, Open University, Milton Keynes, England |
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Abstract: | For a classical system of interacting particles we prove, in the microcanonical ensemble formalism of statistical mechanics, that the thermodynamic-limit entropy density is a differentiable function of the energy density and that its derivative, the thermodynamic-limit inverse temperature, is a continuous function of the energy density. We also prove that the inverse temperature of a finite system approaches the thermodynamic-limit inverse temperature as the volume of the system increases indefinitely. Finally, we show that the probability distribution for a system of fixed size in thermal contact with a large system approaches the Gibbs canonical distribution as the size of the large system increases indefinitely, if the composite system is distributed microcanonically.Supported by The British Council and the Universidad Nacional Autónoma de México. |
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Keywords: | Foundations of statistical mechanics continuity of the temperature Gibbs canonical distribution |
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