Delta and alpha SP(3) C-H bond oxidation of sulfonamides with PhI(OAc)(2)/I(2) under metal-free conditions |
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| Authors: | Fan Renhua Pu Dongming Wen Fengqi Wu Jie |
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| Institution: | Department of Chemistry, Fudan University, Shanghai, China. rhfan@fudan.edu.cn |
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| Abstract: | An efficient delta and alpha sp3 C-H bond oxidation of sulfonamides with PhI(OAc)2/I2 under metal-free conditions has been reported. The reaction provides a useful route to pyrrolidines, N-sulfonylimines, and various sulfonamide derivatives. The potential of this reaction system can be evaluated by its mild condition and simple process. |
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