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Zirconium-mediated conversion of homoallylic ethers into cyclopropane derivatives
Authors:Vincent GandonChristophe Laroche  Jan Szymoniak
Affiliation:Réactions Sélectives et Applications (UMR 6519), CNRS and Université de Reims, 51687 Reims Cedex 2, France
Abstract:Homoallylic ethers react with Cp2ZrCl2/2 n-BuLi reagent to afford cyclopropane derivatives. Cyclopropylcarbinyl-homoallyl rearrangements involving zirconium species are observed depending on the substrate structure.
Keywords:cyclopropanes   homoallylic ethers   rearrangement   zirconium
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