Zirconium-mediated conversion of homoallylic ethers into cyclopropane derivatives |
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Authors: | Vincent GandonChristophe Laroche Jan Szymoniak |
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Affiliation: | Réactions Sélectives et Applications (UMR 6519), CNRS and Université de Reims, 51687 Reims Cedex 2, France |
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Abstract: | Homoallylic ethers react with Cp2ZrCl2/2 n-BuLi reagent to afford cyclopropane derivatives. Cyclopropylcarbinyl-homoallyl rearrangements involving zirconium species are observed depending on the substrate structure. |
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Keywords: | cyclopropanes homoallylic ethers rearrangement zirconium |
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