Synthesis of B2,5 type conformationally constrained glucopyranosides |
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| Authors: | Yves Blé riotSubramanian K Vadivel,Ian R GreigAnthony J Kirby,Pierre Sinaÿ |
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| Affiliation: | a Ecole Normale Supérieure, Département de Chimie, UMR CNRS 8642, 24 rue Lhomond, 75231 Paris Cedex 05, France
b University Chemical Laboratory, Cambridge CB2 1EW, UK |
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| Abstract: | Isopropyl and p-nitrophenyl α- and β-d-glucopyranosides restrained in a conformation close to B2,5 have been synthesized. They are all hydrolyzed at similar rates, close to those observed for the parent unlocked glucosides. |
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| Keywords: | carbohydrates conformation hydrolysis |
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