Ph3BiCO3: a mild reagent for in situ oxidation of urazoles to triazolinediones |
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| Authors: | Cé cilia Mé nardEric Doris,Charles Mioskowski |
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| Affiliation: | CEA/Saclay, Service de Marquage Moléculaire et de Chimie Bioorganique, Département de Biologie Joliot-Curie, 91191 Gif sur Yvette Cedex, France |
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| Abstract: | A novel method for the selective oxidation of urazoles is reported. The resulting triazolinediones are trapped in situ by cycloaddition with anthracene derivatives. The process described herein involves as mild oxidant, the pentavalent bismuth species Ph3BiCO3. |
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| Keywords: | bismuth oxidation triazolinediones urazoles |
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