First enantioselective synthesis and determination of the absolute configuration of natural (+)-dehydro-β-monocyclonerolidol |
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| Authors: | Elie PalomboGé rard Audran,Honoré Monti |
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| Affiliation: | Laboratoire de Réactivité Organique Sélective, UMR 6516 (case 551), Faculté des Sciences et Techniques de St Jérôme, Avenue Escadrille Normandie, Niemen, 13397 Marseille Cedex 20, France |
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| Abstract: | The enantioselective synthesis and determination of the absolute configuration of (+)-dehydro-β-monocyclonerolidol, a natural product isolated from the liverwort P. subobtusa, has been achieved starting from (+)-karahana lactone as an enantiopure building block. Furthermore, the methodology applied provided a new approach towards the known (+)-γ-cyclohomocitral, a key intermediate in the sequence, and natural (+)-pallescensone. |
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