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Enantioselective synthesis of sabina ketone |
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| Authors: | Mario BarberisJulia Pérez-Prieto |
| Abstract: | Both enantiomers of sabina ketone were efficiently prepared via an easy synthesis of 1-diazo-5-methylene-6-methylheptan-2-one, starting from succinic anhydride, followed by its highly enantioselective cyclization catalyzed by chiral dirhodium(II) compounds having ortho-metalated phosphines as ligands. |
| Keywords: | sabina ketone dirhodium(II) compounds asymmetric synthesis |
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