Synthesis and properties of unsymmetrically extended π-electronic conjugation system of octaethylporphyrin(Ni)-dihexybithiophene-octaethylporphyrin(Pd) connected with diacetylene linkage |
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| Authors: | Naoto HayashiAkihito Matsuda Emiko ChikamatsuKazumine Mori Hiroyuki Higuchi |
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| Affiliation: | Department of Chemistry, Faculty of Science, Toyama University, 3190 Gofuku, Toyama, Toyama 930-8555, Japan |
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| Abstract: | Orientational isomers of the diacetylene-group connected dihexybithiophene (DHBTh) derivatives have been synthesized, in which the different octaethylporphyrin (OEP(M); M=Ni or Pd) rings are attached at the ends. Reflecting the unsymmetrical structural feature, the peculiar electronic properties of the extended OEP(Ni)-DHBTh-OEP(Pd) system were observed. |
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