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Novel desilylation of alpha-dimethylsilyl esters by electrochemically generated superoxide ion
Authors:Christos KaimakliotisAlbert J. Fry
Affiliation:Chemistry Department, Wesleyan University, Middletown, CT 06459, USA
Abstract:Electrochemical reduction of oxygen in the presence of an alpha-dimethylsilyl ester results in removal of the dimethylsilyl group. The reaction presumably proceeds by a mechanism involving electrochemically-generated superoxide ion.
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