Extended applications and potential limitations of ring-fused 2,3-oxazolidinone thioglycosides in glycoconjugate synthesis |
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Authors: | Robert J Kerns Congxiang ZhaKamel Benakli Yu-Zeng Liang |
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Institution: | Division of Medicinal & Natural Products Chemistry, University of Iowa, Iowa City, IA 52242, USA |
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Abstract: | The utility of ring-fused 2,3-oxazolidinone derivatives of 2-amino-2-deoxy-thioglycosides in the synthesis of glycopeptide intermediates and building blocks for the synthesis of heparan sulfate oligosaccharides is reported. These unique ring-fused monosaccharides afford a novel and efficient route to alpha-O-linked 2-amino-2-deoxy amino acid derivatives and heparan sulfate oligosaccharide intermediates. |
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