Studies on novel macrocyclization methods of cembrane-type diterpenoids: a Stille cyclization approach to (±)-isocembrene |
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Authors: | Lizeng PengFengzhi Zhang Tiansheng MeiTao Zhang Yulin Li |
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Institution: | National Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China |
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Abstract: | An efficient total synthesis of (±)-isocembrene via an intramolecular Stille cross-coupling reaction is described. A novel strategy towards the 1,3-diene-based cembrane-type macrocyclic diterpenoids has been realized. |
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Keywords: | isocembrene diterpenoids cembranoids Stille reaction |
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