Cross-metathesis, a versatile synthetic methodology for the construction of alkenyl phosphine oxides and bis-phosphine oxides |
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Authors: | F BisaroV Gouverneur |
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Institution: | University of Oxford, The Dyson Perrins Laboratory, South Parks Road, Oxford OX1 3QY, UK |
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Abstract: | Substituted vinyl and allyl phosphine oxides have been prepared by olefin cross-metathesis providing exclusive E olefin stereochemistry. The methodology has been successfully extended to the preparation of various bis-phosphine oxides. |
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