Utility of tetrathiomolybdate and tetraselenotungstate: efficient synthesis of cystine, selenocystine, and their higher homologues |
| |
Authors: | Ramakrishna G BhatEmmanuel Porhiel Vadivelu SaravananSrinivasan Chandrasekaran |
| |
Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India |
| |
Abstract: | Efficient synthesis of cystine, selenocystine, and their higher homologues like homo and bishomo amino acid derivatives from natural amino acid derivatives using tetrathiomolybdate and tetraselenotungstate reagents under mild and neutral conditions is reported. The generality of the reaction has been studied by capping various groups to amino and carboxyl components of canonical amino acids. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|