Palladium-catalyzed stereoselective synthesis of (E)-β,γ-unsaturated amides |
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| Authors: | Fen-Tair Luo Ting-Yi LuCuihua Xue |
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| Institution: | a Institute of Chemistry, Academia Sinica, Nankang, Taipei, Taiwan 11529
b Department of Chemistry and Biochemistry, National Chung Cheng University, Chia-Yi, Taiwan 621 |
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| Abstract: | A facile Suzuki type cross-coupling reaction of alkenylborane with 2-bromo-N,N-dimethylacetamide in the presence of a catalytic amount of tricyclohexylphosphine as the ligand has been demonstrated to be a convenient way for the synthesis of (E)-β,γ-unsaturated amides. |
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| Keywords: | Suzuki coupling reactions alkenylborane 2-bromo-N N-dimethylacetamide |
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