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Highly efficient and versatile acetylation of alcohols catalyzed by cerium(III) triflate |
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| Authors: | Renato DalpozzoAntonio De Nino Loredana MaiuoloAntonio Procopio Monica NardiGiuseppe Bartoli Roberto Romeo |
| Affiliation: | a Dipartimento di Chimica, Università della Calabria, I-87030 Arcavacata di Rende (CS), Italy b Dipartimento di Chimica Organica ‘A. Mangini’, viale Risorgimento 4, I-40136 Bologna, Italy c Dipartimento Farmaco-Chimico Università di Messina ‘A. Mangini’, Viale SS. Annunziata, I-98168 Messina, Italy |
| Abstract: | Cerium(III) triflate is a powerful catalyst for the acetylation of alcohols. The reaction works well for a large variety of simple and functionalized alcohols, without isomerisation of chiral centres. Changes of hydroxyl protective groups are possible in a one-pot procedure. The catalyst can be easily recycled. |
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