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Copper(I)-catalyzed arylselenylation of aryl bromides and iodides
Authors:Irina P Beletskaya  Alexander S SigeevAlexander S Peregudov  Pavel V Petrovskii
Affiliation:a Moscow State University, Chemistry Department, Leninskie Gory, Moscow 119992, Russia
b A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Vavilova str. 28, V-344, Moscow 119991, Russia
Abstract:A new protocol to prepare unsymmetrical diarylselenides using the reaction of aryl bromides and iodides with easily available Bu3SnSeAr catalyzed by Cu(I) complexes under rather mild conditions and with a very high yield is described.
Keywords:diaryl selenides   arylselenation   aryl halogenides   copper-catalyzed   nickel-catalyzed   trialkyltin aryl selenides
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