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Dramatic increase in the rate of the Mukaiyama aldol reaction by ‘fluorous nano flow’ system in the lowest concentration of a fluorous catalyst |
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| Authors: | Koichi Mikami Masahiro YamanakaMd.Nazrul Islam Kenichi KudoNobuko Seino Masaki Shinoda |
| Affiliation: | a Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan b KYA Technologies Corporation, 16-4 Kawa-machi, Hachioji-city, Tokyo 191-0154, Japan c Fuji Electric Co. Ltd, 1 Fuji-machi, Hino-city, Tokyo 191-8502, Japan |
| Abstract: | The reactivity of the Mukaiyama aldol reaction is significantly increased by ‘fluorous nano flow’ system even in the low concentration (<0.0001 M) of a lanthanide fluorous catalyst and the reaction completes within seconds as a contact time in the micro cell. |
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