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Electroreductive intramolecular coupling of aromatic δ- and ε-keto esters
Authors:Naoki Kise  Kie ArimotoNasuo Ueda
Affiliation:Department of Biotechnology, Faculty of Engineering, Tottori University, Koyama, Tottori 680-8552, Japan
Abstract:Electroreduction of aromatic δ- and ε-keto esters in the presence of chlorotrimethylsilane and triethylamine gave five- and six-membered cyclized products. The products were transformed to the corresponding α-hydroxy ketones.
Keywords:electroreduction   reductive coupling   δ-keto esters   ε-keto esters   α-hydroxy ketones
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