Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides |
| |
| Authors: | Antonio Massa,Andrei V. MalkovPavel Ko?ovský ,Arrigo Scettri |
| |
| Affiliation: | a Dipartimento di Chimica, Università di Salerno, Via S. Allende 84081 Baronissi, Salerno, Italy
b Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK |
| |
| Abstract: | Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
