Diastereoselective diallylation of various butane-2,3-diacetals by allylsilane |
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Authors: | Natacha MarietMalika Ibrahim-Ouali Maurice Santelli |
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Affiliation: | Laboratoire de Synthèse Organique, UMR No. 6009, Avenue Escadrille Normandie-Niemen, F-13397 Marseille Cedex 20, France |
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Abstract: | Five butane-2,3-diacetals obtained from the reaction of 1,2-diols and methanol with biacetyl have been treated with allylsilane in the presence of titanium tetrachloride to afford bis-allyldioxanes as single diastereoisomers. |
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