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Formal total synthesis of (±)-magellanine
Authors:Miyuki Ishizaki  Yuka NiimiOsamu Hoshino
Institution:Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2641, Yamazaki, Noda-shi, Chiba 278-8510, Japan
Abstract:Formal total synthesis of magellanine is described. Key features in the synthesis were stereoselective Ireland-Claisen rearrangement and intramolecular Pauson-Khand reaction of exo-cyclic enynes.
Keywords:Pauson-Khand reaction  exo-cyclic enyne  magellanine  total synthesis
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