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Synthesis of thiol substituted oligoanilines for molecular device candidates
Authors:Austen K FlattJames M Tour
Institution:Department of Chemistry and Center for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main Street, Houston, TX 77005, USA
Abstract:The synthesis of thioacetate derivatized oligoanilines designed for molecular electronic device purposes is described. Reversible oxidation between the non-conductive leuco base and conductive emeraldine salt forms of these compounds may produce switching effects and device behavior. The targeted compounds contain a sulfur moiety as a means to connect the molecules to metallic electrodes.
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