1-Fluoropyridinium triflates: versatile reagents for transformation of thioglycoside into O-glycoside, glycosyl azide and sulfoxide |
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| Authors: | Hirokazu Tsukamoto Yoshinori Kondo |
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| Affiliation: | Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Aoba-ku, Sendai 980-8578, Japan |
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| Abstract: | 1-Fluoropyridinium triflates are versatile reagents to transform thioglycoside into O-glycoside, glycosyl azide and sulfoxide. The electronic nature of the substituents on the pyridine ring can control their ability to activate thioglycosides. |
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| Keywords: | 1-fluoropyridinium triflate thioglycoside O-glycoside glycosyl azide glycosyl sulfoxide |
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