Mild and efficient Cs2CO3-promoted synthesis of phosphonates |
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| Authors: | Richard J CohenDaniel L Fox Jarrod F EubankRalph Nicholas Salvatore |
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| Affiliation: | Department of Chemistry, Western Kentucky University, 1 Big Red Way, Bowling Green, KY 42101-3576, USA |
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| Abstract: | A mild and convenient synthesis for phosphonates using cesium carbonate (Cs2CO3), tetrabutylammonium iodide (TBAI) and DMF was developed at room temperature. Numerous dialkyl phosphites were screened using a diverse array of alkyl halides and these reaction conditions were found to be highly efficient producing various phosphonates exclusively in moderate to high yields. |
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| Keywords: | phosphonate dialkyl phosphite cesium carbonate tetrabutylammonium iodide |
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